A buffer solution is prepared by adding NaH2PO4 to a solution of H3PO4 (phosphoric acid).
H3PO4(aq) = H+ (aq) + H2PO4 - (aq)
What happens if HCl is added?

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a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.