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A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. an industrial chemist studying this reaction fills a 25.0l tank with 4.5 mol of sulfur dioxide gas and 4.5 mol of oxygen gas at 30.°c. he then raises the temperature, and when the mixture has come to equilibrium measures the amount of sulfur trioxide gas to be 1.4 mol. calculate the concentration equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. round your answer to 2 significant digits.

13. a covalent bond between two atoms is likely to be polar if: a. one of the atoms is much more electronegative than the other. b. the two atoms are equally electronegative. c. the two atoms are of the same element. d. the bond is part of a tetrahedrally shaped molecule. e. one atom is an anion.