A student weighs 0.347 g of KHP on a laboratory balance. The KHP was titrated with NaOH and the concentration of the NaOH determined to be 0.110 M. For the second titration, the student correctly diluted 6 M HCl from the reagent shelf using a graduated cylinder to obtain approximately 0.6 M HCl. This solution was titrated with the original NaOH solution. The student calculated the concentration of NaOH from the experiment to be 0.099 M. In which experiment should the student be more confident of the concentration of the NaOH solution

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. in the first step, calcium carbide and water react to form acetylene and calcium hydroxide: cac2 (s) + 2h2o (g) → c2h2 (g) + caoh2 (s) =δh−414.kj in the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6c2h2 (g) + 3co2 (g) + 4h2o (g) → 5ch2chco2h (g) =δh132.kj calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. round your answer to the nearest kj .