Is NaHCO3 a binary compound​

No

Explanation:

Binary compounds contain only 2 distinct elements.

For example magnesium oxide MgO is a binary compound.

NaHCO3 contains 4 distinct elements.

answer is: naturally occurring solid, inorganic compound or element is mineral.

minerals usually have crystalline form, that means than crystal constituents (atoms, molecules or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions.

for example magnetite is a mineral of iron oxide (fe₂o₃).

calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (caco₃).

dolomite is an   carbonate mineral composed of calcium magnesium carbonate (camg(co₃)₂).