How many unpaired electrons are in the following complex ions? a. Ru(NH3)62+ (low-spin case)
b. Ni(H2O)62+
c. V(en)33+

Solution :

A complex ion may be defined as a metal ion that is located at the center with other molecules or ions surrounding the center ion.

In the context, the number of the unpaired electrons for the following complex ions are :

1.  (low spin)

   Here all the d-electrons are paired. Therefore, there are no unpaired electrons.

2.  (high spin)

   Therefore, it has two unpaired electrons.

3.  (high spin)

   It has 2 unpaired electrons

explanation:

metals have excess of electrons whereas non-metals have deficiency of electrons. thus, in order to gain stability metals easily donate their electrons to the non-metals.

for example, electronic configuration of sodium is and electronic configuration of phosphorous is .

when a phosphorous atom and sodium atom combine together then sodium will donate is extra one electron to the phosphorous atom. as a result there will be formation of ionic bond between sodium and phosphorous.

the reaction will be as follows.

there, are three sodium sodium atoms and each of them will donate its one extra electron to phosphorous atom. thus, the sub-shell of phosphorous gets completely filled.  

thus, we can conclude that electrons are transferred from atoms of sodium to atoms of phosphorous. this transfer makes the sodium atoms donate one electron and the phosphorous atoms to gain one electron. as a result, the sodium and phosphorus atoms strongly attract each other.