What is the temperature of a 6.1 mole sample of He gas at 18.5 bar and volume of 115L pleaseee help asappp

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The bond energy for the van der waals bond between two helium atoms is 7.9×10−4ev. assuming that the average kinetic energy of a helium atom is (3/2)kbt, at what temperature is the average kinetic energy equal to the bond energy between two helium atoms

Before it was launched, a helium-filled balloon had a pressure of 201 kpa at a temperature of 27°c. at an altitude of 15,000 m, the pressure had decreased to 2.5 kpa and the temperature had dropped to -14 °c. the volume of the balloon increased to 59.3 m3. what is the original volume of the balloon? 13 m3 0.85 m3 0.077 m3 1.17 m3