15. NH4Cl(aq) + Pb(NO3)2(ag)

☆ionisation energy increases across a period from na -> ar☆ionisation energy decreases down a group from li -> fr☆ionic radius decreases across a period from na -> cl☆ionic radius increases down a groupfrom f -> ii hope it clarifies your doubts

Hbr dissociates to form h+ and br-ca(oh)2 dissociates to form ca2+ and 2oh-the h+ and oh- react to form waterassuming the reactants are dissolved in water, the net reaction is h+ + oh- —> h2oif you’re asked to show all components of the reaction, the complete reaction is 2hbr + ca(oh)2 —> cabr2 + 2h2o

Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.