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Chemistry, 27.06.2021 14:00 ridjebeberjejej7502

Need help asap - There is an error in the rate-determining step of the following proposed mechanism. Slow step: CH3(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]
Fast step: CH3(g) + Cl2(g) → CH3Cl(g) + Cl–(g) and the rate rule is k2 = [CH4][Cl2]
Overall : CH4(g) + 2Cl2(g) → CH3Cl(g) + HCl(g) + Cl–(g)

Which shows the correct rate-determining step for the mechanism?

CH4(g) + 2Cl(g) → CH3Cl(g) + HCl(g) + Cl–(g)
CH4(g) + Cl2(g) → CH3(g) + HCl(g) and the rate rule is k1 = [CH4][Cl2]
CH4(g) + Cl2(g) → CH3Cl(g) + Cl–(g) and the rate rule is k2 = [CH4][Cl2]
CH3(g) + 2Cl2(g) → CH3Cl(g) + Cl–(g) and the rate rule is k2 = [CH4][Cl2]

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