Using a value of ksp = 1.8 x 10-2 for the reaction pbcl2 pb+2(aq) + 2cl -(aq). if the value of ksp was determined to be only 1.2 x 10-2: too much solid has dissolved. additional precipitate is forming. the solution is unsaturated. the ions are now combining to reduce their concentrations.
The big bang nucleosynthesis theory states that elements were produced in the first few minutes of the big bang while elements have their origins in the interiors of stars, forming much later in the history of the universe.