13. Acid catalyzed dehydration-condensation reactions of carboxylic acids and alcohols produce chemicals called esters.
i. Using carbon skeletal notation, write the dehydration-condensation reaction that occurs between ethanol
and butanoic acid.
ii. What is the name of this ester?

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole

the term hydride is commonly named after binary compounds that hydrogen forms with other elements of the periodic table. hydride compounds in general form with almost any element, except a few noble gases. the trends and properties vary according to the type of intermolecular force that bonds the elements together, the temperature, its molecular masses, and other components. hydrides are classified into three major groups, depending on what elements the hydrogen bonds to. the three major groups are covalent, ionic, and metallic hydrides. formally, hydride is known as the negative ion of a hydrogen, h-, also called a hydride ion. because of this negative charge, hydrides have reducing, or basic properties. its special characteristics will be further discussed.

explanation: