• The heat of reaction N₂ + 3H₂+ 2NH, at 27°C was found to be -21.976 kcal. What will be the heat of reaction at 50°C ? The molar heat capacities at constant pressure and at 27°C for nitrogen, hydrogen and ammonia are 6.8, 6.77 and 8.86 cal mol-¹ degree-¹. (Ans = 22.192kcal

Two nitro no2 groups are chemically bonded to a patch of surface. they can't move to another location on the surface, but they can rotate (see sketch at right). it turns out that the amount of rotational kinetic energy each no2 group can have is required to be a multiple of ε, where =ε×1.010−24 j. in other words, each no2 group could have ε of rotational kinetic energy, or 2ε, or 3ε, and so forth — but it cannot have just any old amount of rotational kinetic energy. suppose the total rotational kinetic energy in this system is initially known to be 32ε. then, some heat is removed from the system, and the total rotational kinetic energy falls to 18ε. calculate the change in entropy. round your answer to 3 significant digits, and be sure it has the correct unit symbol.

The reactions shown here can be combined to make the overall reaction c(s) + h2o(g) ⇌ co(g) + h2(g) by reversing some and/or dividing all the coefficients by a number. a. c(s) + o2(g) → co2(g) k=1.363×10^69 b. 2 h2(g) + o2(g) → 2 h2o(g) k=1.389×10^80 c. 2co(g) + o2 (g) → 2 co2(g) k=1.477×10^90

The human eye contains a molecule called 11-cis-retinal that changes shape when struck with light of sufficient energy. the change in shape triggers a series of events that results in an electrical signal being sent to the brain that results in vision. the minimum energy required to change the conformation of 11-cis-retinal within the eye is about 164 kj/mol.