How much will atmospheric carbon change in one year, 10 years and 100 years? (From Carbon Cycle Gizmo)

For the reaction shown, find the limiting reactant for each of the following initial amounts of reactants. 4al(s)+3o2(g)→2al2o3(s) a) 1 molal, 1 mol o2 b) 4 molal, 2.6 mol o2 c) 16 molal, 13 mol o2 d) 7.4 molal, 6.5 mol o2