4. A student added 75 mL instead of 40 mL of water to the acetic acid in the Erlenmeyer flask prior to titrating with NaOH. Will the student's calculated
acetic acid molarity be higher, lower, or no different than the correct
value? Explain.

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d

explanation:

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.