Which scientific tools are used by life scientists

Ineed ! i have no clue how to do this problem.

The content of manganese (mn) in steel was determined spectrophotometrically and with the use of the standard addition method. an unknown sample of mn from a digested steel sample gave an absorbance of 0.185 when analyzed spectrophotometrically. when 5.00 ml of solution containing 95.5 ppm mn was added to 50.0 ml of the unknown steel solution (digested sample), the absorbance was 0.248. calculate the concentration, in parts-per-million (ppm), of mn in the digested steel sample solution.

Ammonium perchlorate nh4clo4 is the solid rocket fuel used by the u.s. space shuttle. it reacts with itself to produce nitrogen gas n2 , chlorine gas cl2 , oxygen gas o2 , water h2o , and a great deal of energy. what mass of nitrogen gas is produced by the reaction of 2.1g of ammonium perchlorate?