In a be atom a 1s electron has a greater zeff than a 2s electron true or false

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?

If anyone would be able to me out with these three questions it would be these are from the chem 2202 course.

One of the hopes for solving the world's energy problem is to make use of the fusion reaction 21h +31h --> 42he + 10n + energy how much energy is released when 1 mol of deuterium is fused with 1 mol of tritium according to the above reaction? the masses of the atoms and the neutrons are as follows: 21h = 2.0140 amu 31h = 3.01605 amu 42he = 4.002603 amu 10n = 1.008665 amu. the speed of light is 2.9979 x 108 m/s.