Chemistry, 26.07.2019 15:00 chrismax8673

Pyridine (c5h5n) is a particularly foul-smelling substance used in manufacturing pesticides and plastic resins. calculate the ph of a 0.115 m solution of pyridine (kb = 1.4×10-9 ).

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Answer from: brennanjb00

Answer is: ph value of pyridine solution is 9.1.

Chemical reaction: C₅H₅N + H₂O → C₅H₅NH⁺ + OH⁻.
c(pyridine - C₅H₅N) = 0.115M.
Kb(C₅H₅N) = 1.4·10⁻⁹.
[C₅H₅NH⁺] = [OH⁻] = x; equilibrium concentration.
[C₅H₅N] = 0.115 M - x.

Kb = [C₅H₅NH⁺] · [OH⁻] / [C₅H₅N].

1.4·10⁻⁹ = x² / (0.115 M -x)

Solve quadratic equation: x = [OH⁻] = 0.0000127 M.
pOH = -log(0.0000127 M) = 4.9

pH = 14 - 4.9 = 9.1.

Answer from: Quest

1.from liquid state to gaseous state is evaporation 3.solid to liquid is melting 5. solid to gaseous state is sublimation 6. gas to solid state is decomposition 7. a change of state is known as the states of matters

Answer from: Quest

assuming that your periodic table has eighteen columns, you should highlight the four elements in the third column from the left of the table.

explanation

neutral atoms of elements after calcium contain d electrons. the energy of d orbitals of a particular main shell lies between the energy of the s and p orbitals of the next main shell. for example, electrons in the $3d$ have energy higher than those in the $4 s$ orbital while lower than those of the $4 p$ orbital.

by the aufbau principle, electrons fill orbitals one at a time, starting from those of the lowest energy. the $4s$ orbital is therefore filled right after $3p$ orbitals and before $3 d$ orbitals.

potassium has electron configuration $[\text{ar}] 4 s^{1}$ and calcium $[\text{ar}] 4 s^{2}$ . the s orbital of a main shell holds a maximum of two electrons. the next element would thus have the electron configuration $[\text{ar}] 4 s^{2} \; 3d^{1}$ and satisfy the requirements.

a neutral atom of the element contains three electrons on top of the most recent noble gas element. it should thus be placed in the third column of the periodic table. both scandium and yttrium would satisfy the conditions. an aufbau diagram indicates that the 4f orbital is filled before the 5d. however, it appears that exceptions exists for both lanthanum and actinium. neutral atoms of the two d-block elements also demonstrate the $ns^{2} \; (n-1) p^{1}$ and should be highlighted as well.

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