Compound a undergoes ionization to form compound b as indicated below. using the compound b, draw the mechanism which account for the formation of the abundant ion at m/z=113 using fish-hook arrow. include lone pairs and charges in your answer. do not draw any of hydrogen atoms explicitly.

Aloaded platform of total mass 500 kg is supported by a dashpot and by a set of springs of effective stiffness 72 kn/m. it is observed that when the platform is depressed through a distance x = 12.5 cm below its equilibrium position and then released without any initial velocity; it reaches its equilibrium position in the shortest possible time without overshoot. find the position and velocity of the loaded platform 0.10 sec. after its release. if a further load of 400 kg is added to the platform, find, i) the frequency of damped vibrations, and i) the amplitude of vibration after 2 complete oscillations, given that the initial amplitude is 15 cm.

Coiled springs ought to be very strong and stiff. si3n4 is a strong, stiff material. would you select this material for a spring? explain.

Afour cylinder four-stroke in-line engine has a stroke of 160mm, connecting rod length of 150mm, a reciprocating mass of 3kg and its firing order is 1-3-4-2. the spacing between cylinders is 100mm. i. show that the engine is in balance with regard to the primary inertia forces and primary 3. a and secondary inertia couples. li determine the out of balance secondary inertia force ii. propose ways of balancing this out of balance force and discuss the challenges that will arise