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Describe one experiment in which the glass transition temperature and melting temperature of a totally amorphous thermoplastic material can be determined. show the relevant experimental results in a diagram which should be properly annotated with the two temperatures clearly marked. what is likely to happen to the curve in the diagram if the amorphous polymer is replaced by a thermosetting type?

Atank with constant volume contains 2.27 kg of a mixture of water phases (liquid-vapor). in the initial state the temperature and the quality are 127 °c and 0.6, respectively. the mixture is heated until the temperature of 160 oc is reached. illustrate the process in a t-v diagram. then, determine (1) the mass of the vapor in kg at the initial state, (2) the final pressure in kpa.

Amixture of slurry and mud is to be pumped through a horizontal pipe of diameter 500 mm. the fluid behaves as a bingham plastic with a yield stress of 30 pa and viscosity 0.04 pa.s. describe the effects of the shear stress through a transverse section of the pipe by plotting the variation in shear stress and velocity profile: (i) just before the slurry starts to move (ii) as the slurry flows when the pressure gradient is double that in part (i)