How are conjunctive adverb and subordinate adverbs difference

Conjunctive adverb is an adverb or adverbial phrase that indicates a relation in meaning between two sequential independent clauses (or main clauses). It is also called a conjunct, a transitional conjunction, or a cohesive conjunction.

subordinate adverbial clauses function within sentences as adverbs. Just as most adjective clauses begin with a relative pronoun, adverb clauses always begin with a subordinating conjunction (after, before, unless, although, when, while, as soon as, as long as, as if, where etc) marking them as grammatically subordinate
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