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Which statements are true? see picture

Jeffery conducted a survey in his school and found that 30 of the 50 eighth grade students' favorite subject is mathematics. based on the results, jeffery concluded that out of the 200 students in his school, 120 students' favorite subject is mathematics. select the statement that is true about jeffery's conclusion. a. jeffery's conclusion is not valid because the sample was biased since only 200 students were surveyed. b. jeffery's conclusion is valid because the sample was random since all of the students were eighth grade students. c. jeffery's conclusion is valid because the sample was random. d. jeffery's conclusion is not valid because the sample was biased since all of the students were eighth grade students.

Consider the reaction 2x2y2+z2⇌2x2y2z which has a rate law of rate= k[x2y2][z2] select a possible mechanism for the reaction.