Please help me to solve this two question as soon as possible. Thank you.

Which operation should be performed first according to the order of operations? 44 • 2 – [(5 + 20 • 3) – 12] + 16 ÷ 2 5 + 20 20 • 3 16 ÷ 2 44 • 2

Sara can take no more than 22 pounds of luggage on a trip.her suitcase weighs 112 ounces.how many more pounds can she pack without going over the limit?

Neoli is a nurse who works each day from 8: 00 am to 4: 00 pm at the blood collection centre. she takes 45 minutes for her lunch break. on average, it takes neoli 15 minutes to collect each sample and record the patient's details. on average, how many patients can neoli see each day?