Air is held within a frictionless piston-cylinder container, which is oriented vertically. the mass of the piston is 0.45 kg and the cross-sectional area is 0.0030 m2. initially (state 1) the pressure of the gas is sufficient to support the weight of the piston as well as the force exerted by the atmospheric pressure ( 101.32 kpa). the volume occupied by the air within the cylinder in state 1 is 1.00 liter. one end of a spring (with spring constant k = 1000 n/m) is attached to the top of the piston, while the other end of the spring is attached to a stage that can move vertically. initially the spring is undeflected and therefore exerts no force. then the stage is then moved quasistatically downward a distance of 10.0 cm, at which point the system reaches state 2. the piston-cylinder is not insulated; rather it remains in diathermal contact with the surroundings, which are at a constant temperature of 300 k. what is the change of pressure within the container?

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mass and volume are the answers you are looking for

scattering of light by tiny particles in air to produce the colors we see on sky, is dependent on the following factors:

(i) wavelength of light

(ii) size of the scattering particle  

(iii) distance traveled by light through the atmosphere.

according to rayleigh's law of scattering, the amount of scattering is inversely proportional to the fourth power of its wavelength. shorter the wavelength, greater is its scattering. hence violet/blue light is scattered more than red.

sun's light is a composite light ( visible light) with wavelengths in the range 400 nm (violet) to 700 nm (red). as sunlight passes through our atmosphere, the molecules of air scatter light according to their wavelengths. during sunrise and sunset, the sun's position is below the horizon. hence light from the sun travels a greater distance in the atmosphere when compared to its position a noon.

as sunlight enters the earth's atmosphere, blue light is scattered away and at the end of its journey in the sky, only red and orange wavelengths remain in the beam.

hence at sunrise and sunset, the sky appears reddish orange.