Three discrete spectral lines occur at angles of 10.0°, 13.6°, and 15.0°, respectively, in the first-order spectrum of a diffraction grating spectrometer.
(a) if the grating has 3750 slits/cm, what are the wavelengths of the light?
λ1 = nm (10.0°)
λ2 = nm (13.6°)
λ3 = nm (15.0°)
(b) at what angles are these lines found in the second-order spectra?
θ = ° (λ1)
θ = ° (λ2)
θ = ° (λ3)

Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele

As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.

The intensity of a polarized electromagnetic wave is 12 w/m^2. part a) what will be the intensity after passing through a polarizing filter whose axis makes the angle θ=0∘ with the plane of polarization? part b) what will be the intensity after passing through a polarizing filter whose axis makes the angle θ=30∘ with the plane of polarization? part c) what will be the intensity after passing through a polarizing filter whose axis makes the angle θ=45∘ with the plane of polarization? part d) what will be the intensity after passing through a polarizing filter whose axis makes the angle θ=60∘ with the plane of polarization? part e) what will be the intensity after passing through a polarizing filter whose axis makes the angle θ=90∘ with the plane of polarization?