Typically, the vibrational energies of a molecule are larger than the rotational energies. however, this will not always be the case. in this problem we would like to investigate a molecule where the rotational energies exceed the vibrational energies 1. figure 9.30 illustrates the combined rotational-vibrational structure when the vibrational energy is much larger than the rotational energy. make a sketch showing the reverse situation, in which the rotational energy is much larger than the vibrational energy. use a scale in which b-0.10 ev and hf-0.02 ev; show rotational levels up to l=3 and vibrational levels up to n=3. 2. show all of the possible absorption transitions on your sketch that satisfy the selection rules. 1. find the energies and wavelengths associated with each of these transitions. in what portion of the electromagnetic spectrum do these transitions lie? construct a diagram, similar to figures 9.31 and 9.32, showing what the expected spectrum would look like (do not worry about the relative intensities of the emission lines). (2 points) in addition to the wavelengths of the emitted photons, the relative intensity of the photons can also tell us something about the molecular structure - in particular the relative size of the b constant related to the rotational energies. the most intense absorption lne in the rotational-vibrational structure of co at room temperature occurs for l-7. justify this value with a calculation. (the equilibrium separation of co is 0.113 nm. see equation 9.16.)