Determine the lattice vectors a, b and c of the primitive unit cell for the face-centred cubic lattice in terms of cartesian unit vectors i, j and k. assume the cube has side length a. (b) prove that the cell bounded by your vectors is a primitive cell. (c) assume that there is a single spherical atom at each lattice point of the foc lattice, and that these atoms pack the volume as densely as possible (close-packed). determine the fraction of volume that is occupied by "atoms” in this structure. (note, this is called the packing fraction.)

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Fill in the blanks with the numbers is a measure of the resistance to flow. a high liquid has a high resistance to flow and flows slowly. the ancients thought everything in the world was made of 4 we now know that there are 94 naturally occurring and scientists have created another 24 i am certain they will create even more. honey flows slowly because it has a high to flowing. a can be separated by physical means because it contains more than one pure substance and 2 pure substances are not chemically bonded to each other. a cannot be separated by physical means. all matter is made up of all elements are with the same number of protons. if it is just a single or many bonded together, if all of them have the same number of protons, it is an element. in a piece of pure iron metal, all the are joined together, that piece of iron metal is called elemental iron. a single of iron is called elemental iron. a mixture has differences from place to place. we might need a microscope to see them or they might be obvious to the unaided eye. there are surfaces separating it into different phases. a mixture is the same everywhere. it is uniform. there are no surfaces separating it into different phases. if different kinds of atoms (different elements) are bonded together by their electrons, it is called a there are physical means of to isolate the different pure substances in a mixture and there are chemical means of to isolate the different elements in a compound. 1. element 2. compound 3. mixture 4. heterogeneous 5. homogeneous 6. pure substance 7. atoms 8. separation 9. viscosity 10. resistance

Arefrigerator uses r-134a as the working fluid and operates on the ideal vapor-compression refrigeration cycle except for the compression process. the refrigerant enters the evaporator at 120 kpa with a quality of 34 percent and leaves the compressor at 70°c. if the compressor consumes 450 w of power, determine (a) the mass flow rate of the refrigerant, (b) the condenser pressure, and (c) the cop of the refrigerator. (0.00644 kg/s, 800 kpa, 2.03)