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The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

In a stagnant pool of water, a crayfish may spend much of its time lying with one side of its carapace near the surface of the water. in this position, it will move the walking legs on that side in a rhythmic back-and-forth motion. explain the likely function of this behavior.

Waves are used in many practical applications to support work, entertainment, and health. one example is the use of ultrasound imaging to safely track the development of a growing fetus. what is a specific example of a practical application of waves in medicine, entertainment, safety, or other fields? provide a brief explanation of how the properties of waves are useful to that application.