Ascientist mixes an unknown powder into a beaker of water. he then uses an indicator and finds that the ph of the resulting solution is 8.5. what can he infer from this observation?

the unknown powder was acidic.
the unknown powder decreased the hydrogen ion concentration of the water.
the indicator used can measure only basic solutions.
the powder contains hydrogen ions.

An internally reversible refrigerator has a modified coefficient of performance accounting for realistic heat transfer processes of where qin is the refrigerator cooling rate, qout is the heat rejection rate, and is the power input. show that copm can be expressed in terms of the reservoir temperatures tc and th, the cold and hot thermal resistances rt,c and rt,h, and qin, as where rtot rt,c rt,h. also, show that the power input may be expressed as 1.39 a household refrigerator operates with cold- and hot-temperature reservoirs of tc 5 c and th 25 c, respectively. when new, the cold and hot side resistances are rc,n 0.05 k/w and rh,n 0.04 k/w, respectively. over time, dust accumulates on the refrigerator’s condenser coil, which is located behind the refrigerator, increasing the hot side resistance to rh,d 0.1 k/w. it is desired to have a refrigerator cooling rate of qin 750 w. using the results of problem 1.38, determine the modified coefficient of performance and the required power input w under (a) clean and (b) dusty coil conditions. internally reversible refrigerator qout qin w high-temperature reservoir low-temperature reservoir th th,i tc,i tc high-temperature side resistance low-temperature side resistance w qin th tc qinrtot tc qinrtot copm tc qinrtot th tc

As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.

Some material consisting of a collection of microscopic objects is kept at a high temperature. a photon detector capable of detecting photon energies from infrared through ultraviolet observes photons emitted with energies of 0.3 ev, 0.5 ev, 0.8 ev, 2.0ev, 2.5ev, and 2.8ev. these are the only photon energies observed. (a) draw and label a possible energy-level diagram for one of the microscopic objects, which has four bound states. on the diagram, indicate the transitions corresponding to the emitted photons. explain briefly. (b) would a spring–mass model be a good model for these microscopic objects? why or why not? (c) the material is now cooled down to a very low temperature, and the photon detector stops detecting photon emissions. next, a beam of light with a continuous range of energies from infrared through ultraviolet shines on the material, and the photon detector observes the beam of light after it passes through the material. what photon energies in this beam of light are observed to be significantly reduced in intensity (“dark absorption lines”)? explain briefly.