When do we say that work is done?​

The energy released by a chemical reaction can be measured using a calorimeter. when barium hydroxide octahydrate crystals are reacted with dry ammonium chloride inside of a coffee cup calorimeter, the temperature of the 18.00 g of water in the calorimeter decreases from 30.0°c to 8.0°c. the equation for calculating energy absorbed or released by a reaction is: where q is the energy released or absorbed, m is the mass of water in the calorimeter, cp is the specific heat of water, and δt is the observed temperature change. if the specific heat of liquid water is 4.19 j/g·°c, how much energy was absorbed by the reaction?

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Asap and show ! a 14 kg rock starting from rest free falls through a distance of 5.0 m with no air resistance. find the momentum change of the rock caused by its fall and the resulting change in the magnitude of earths velocity. earth mass is 6.0 * 10^24 kg. show your work assuming the rock earth system is closed.