Also not sure about this one

The pressure, volume, and temperature of a mole of an ideal gas are related by the equation pv = 8.31t, where p is measured in kilopascals, v in liters, and t in kelvins. use differentials to find the approximate change in the pressure if the volume increases from 14 l to 14.6 l and the temperature decreases from 375 k to 370 k. (round the answer to two decimal places.)

When the displacement of a mass on a spring is 12a the half of the amplitude, what fraction of the mechanical energy is kinetic energy? at what displacement, as a fraction of a, is the mechanical energy half kinetic and half potential?

(a) if the pressure in gas is doubled while its volume is held constant, by what factor do (i) vrms and (ii) change? (b) is it possible to boil water at room temperature (20oc) without heating it? explain.