A researcher studying the nutritional value of a new candy places a 4.20 g sample of the candy inside a bomb calorimeter and combusts it in excess oxygen. The observed temperature increase is 2.91 ∘ C. If the heat capacity of the calorimeter is 46.80 kJ ⋅ K − 1 , how many nutritional Calories are there per gram of the candy?

Answer asap need by wednesday morning explain how a buffer works, using an ethanoic acid/sodium ethanoate system including how the system resists changes in ph upon addition of a small amount of base and upon addition of a small amount of acid respectively. include the following calculations in your i. calculate the ph of a solution made by mixing 25cm3 0.1m ch3cooh and 40cm3 0.1m ch3coo-na+. [ka = 1.74 x 10-5 m] ii. calculate the ph following the addition of a 10cm3 portion of 0.08 m naoh to 500cm3 of this buffer solution. iii. calculate the ph following the addition of a 10cm3 portion of 0.08 m hcl to 200cm3 of the original buffer solution.