A particular refrigerator cools by evaporating liquefied dichlorodifluoromethane, CCl2F2. How many kilograms of this liquid must be evaporated to freeze a tray of water at 0°C to ice at 0°C? The mass of the water is 571 g, the heat of fusion of ice is 6.02 kJ/mol, and the heat of vaporization of dichlorodifluoromethane is 17.4 kJ/mol.

1.33 kilograms of this liquid must be evaporated to freeze a tray of water at 0°C to ice at 0°C.

Explanation:

Let the mass of liquefied dichlorodifluoromethane be x.

Mass of water to freeze = 571 g

Moles of water =

Heat of fusion of ice = 6.02 kJ/mol

Heat lost when 1 mole of water freeze's = -6.02kJ/mol

Heat lost when 31.7 moles of water freeze's: Q

Heat required to evaporate x amount of liquefied dichlorodifluoromethane: Q'

Q'= -(Q) = 191. kJ

Moles of liquefied dichlorodifluoromethane =

Heat of vaporization of dichlorodifluoromethane = 17.4 kJ/mol

Solving for x:

x = 1328.2 g = 1.33 kg

1 g = 0.001 kg

1.33 kilograms of this liquid must be evaporated to freeze a tray of water at 0°C to ice at 0°C.

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