The amount of UVA radiation hitting a surface at sea level in a lightly clouded day is about 70W/m2. About half of that can be absorbed by the skin. A typical carbon- carbon bond requires 348 kJ/mol to break. A person lies on the beach for about 1 hour without sunscreen (i. e. fully exposed to UVA radiation). Estimate the number of C-C bonds broken in this person’s back (about 0.18 m2) over that period. Assume that the average wavelength of UVA is 335 nm.

The zinc within a copper-plated penny dissolves in hydrochloric acid if the copper coating is filed down in several spots (so that the hydrochloric acid can reach the zinc). the reaction between the acid and the zinc 2h+(aq)+zn(s)→h2(g)+zn2+(aq) . when the zinc in a certain penny dissolves, the total volume of gas collected over water at 25 °c is 0.947 l at a total pressure of 743 mmhg . (vapor pressure of water is 23.78 mmhg at 25 °c .) what mass of hydrogen gas is collected? answer in appropriate significant figures