Is hand washing a chemicals change or physicals change and why?

Asample of silver (with work function ? = 4.52 ev) is exposed to an ultraviolet light source (? = 200 nm), which results in the ejection of photoelectrons. what changes will be observed if: silver is replaced with copper (? = 5.10 ev) more photoelectrons ejected no photoelectrons are emitted fewer photoelectrons ejected more energetic photoelectrons (on average) less energetic photoelectrons (on average)

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.

0.2348 grams of pbcl2 used to form 44.0 ml of solution.