if reaction 2 (figure 4) is repeated with hcl and the compound shown below, which of the following compounds is not a direct product (without rearrangement)?

You would be correct, boiling water does disinfect contamination.    the property of disinfecting means to kill  germs, bacteria and other pathogens or contamination  that might cause an infection or cause a person to become sickly. a couple methods of disinfecting are using soap, other cleaning supplies or by simply "boiling" the contaminate.  the reason why boiling water disinfects certain attributes is because some cells cannot survive the heat and pressure.

Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.