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The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

The ksp expression for the system pbcl2(s) pb+2(aq) + 2 cl-(aq) is: [pbc12][pb+2][2cl-] [pb+2][cl-]2 [pb+2][2cl-]2 [pbcl2][pb+2][cl-]2 [pb+2][2cl-]2[pbcl2]

Which of the following is true for the relation f(x)=2x^2+1