I really need help can anyone help

1. how much energy is needed to raise the temperature of 40.0 g of argon from 25c to 40c? the specific heat capacity of argon is 0.520 j/(g·k) 2a. 23.0 ml of 0.100 m hcl (standard) are added from a buret to neutralize 50.0 ml of an unknown basic solution. 2b. if the oh- produced in the previous reaction came from ca(oh)2, then what is the molarity of the ca(oh)2? 3.calculate the new freezing-point of a solution when 60.5 grams of cacl2 solute is dissolved in 0.612 kg of water. 4. what is the maximum number of moles of alcl3 that can be produced from 5.0 mol al and 6.0 mol cl2? 5. a sample of oxygen gas has a volume of 150 ml when its pressure is 0.923 atm. if the pressure is increased to 0.987 atm and the temperature remains constant, what will the new volume be? 6. nitrogen gas in a closed container at a temperature of 100.0 oc and 3.0 atm is heated to 300 oc. what is the pressure of the gas at the higher temperature?

Suppose a wheel with a tire mounted on it is rotating at the constant rate of 2.15 times a second. a tack is stuck in the tire at a distance of 0.373 m from the rotation axis. noting that for every rotation the tack travels one circumference (a) find the tack's tangential speed. (b) what is the tacks radial acceleration?

As you are trying to move a heavy box of mass m, you realize that it is too heavy for you to lift by yourself. there is no one around to , so you attach an ideal pulley to the box and a massless rope to the ceiling, which you wrap around the pulley. you pull up on the rope to lift the box. use g for the magnitude of the acceleration due to gravity and neglect friction forces. once you have pulled hard enough to start the box moving upward, what is the magnitude f of the upward force you must apply to the rope to start raising the box with constant velocity? express the magnitude of the force in terms of m, the mass of the box.